Synthesis and Characterization of Some New Metals Complexes of [N-( 4-chlorobenzoyl amino )-thioxomethyl] Anthranilic Acid (CBA)

  • Basima Mohsen Sarhan Department of Chemistry , College of Education for Pure Sciences ,Ibn-AL-Hatham ,University of Baghdad
  • Murtadha A. Farhan
Keywords: Anthranilic acid, 4-chloro benzoyl isothiocyanate, complexes

Abstract

A new ligand [N-(4-chloro benzoyl amino)-thioxo methyl] anthranilic acid (CBA) was synthesized by reaction of 4chlorobenzoyl isothiocyanate with anthranilic acid by using acetone as a solvent , The ligand was characterized by elemental analysis ,FT-IR,and13C, 1H-NMR spectra, some transition metals complexes of this ligand was prepared and characterized by FT-IR, UV-Visible spectra , conductivity measurements , magnetic susceptibility , atomic absorption and molar ratio ( M : L ). From results obtained ,the following formula [ M (CBA )2 ] where M+2 = Mn, Co , Ni , Cu , Pd , Zn , Cd ,and Hg , the proposed molecular structure for these complexes as tetrahedral geometry except copper and palladium complexes are have square planer geometry .

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Published
2017-08-02
How to Cite
Sarhan, B. M., & Farhan, M. A. (2017). Synthesis and Characterization of Some New Metals Complexes of [N-( 4-chlorobenzoyl amino )-thioxomethyl] Anthranilic Acid (CBA). Al-Qadisiyah Journal of Pure Science, 19(4), 150-165. Retrieved from https://journalsc.qu.edu.iq/index.php/JOPS/article/view/293
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Articles