Synthesis and Characterization of Some New Metals Complexes of [N-( 4-chlorobenzoyl amino )-thioxomethyl] Anthranilic Acid (CBA)
Abstract
A new ligand [N-(4-chloro benzoyl amino)-thioxo methyl] anthranilic acid (CBA) was synthesized by reaction of 4chlorobenzoyl isothiocyanate with anthranilic acid by using acetone as a solvent , The ligand was characterized by elemental analysis ,FT-IR,and13C, 1H-NMR spectra, some transition metals complexes of this ligand was prepared and characterized by FT-IR, UV-Visible spectra , conductivity measurements , magnetic susceptibility , atomic absorption and molar ratio ( M : L ). From results obtained ,the following formula [ M (CBA )2 ] where M+2 = Mn, Co , Ni , Cu , Pd , Zn , Cd ,and Hg , the proposed molecular structure for these complexes as tetrahedral geometry except copper and palladium complexes are have square planer geometry .
Downloads
Copyright © Author(s) . This is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.