Synthesis and characterization of azo amidazole ligand type N2 and metal complexes with di valence cobalt , nickel and copper
Keywords:
binzial, hexa methylene tetra amine, diazanium chloride
Abstract
The bi dentate ligand type N2 have been prepared through two steps . The first included the reaction between one equivalent of benzil with one equnivalent of hexa methylene tetra amine, the second included the reaction of first step precursor with one equnivalent of diazanium chloride ( p- ethyle aniline with acidic sodium nitrate ) , to obtained the target ligand . Co+2 , Ni+2 , Cu+2 from there action of the ligand Complexes were prepared with metal ions 1:1 ratio , the prepousd compounds were characterized by FT-IR , UV-Vis , NMR for ligand , C.H.N Elemental analysis spectoscopies , as well as the molar conductivity and magneticthe successptibility . suggested geometry around the cobalte and copper ions is octahedral and Square planer around nickel ion.Downloads
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3. Gung.B, Taylor.R, 2004, Parallel Combinatorial Synthesis of Azodyes, J. Chem., 1630,11.
4. Patal.S, 1975, The Chemistry of Hydrazo , Azo and Azoxy Group, Ed1st, John Wileg and Sons., London, New York .
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6. Lycka.A and Hole+++++++cek.J, 2003, Dyes and Pigments., 57, 115.
7. Pozharskil.A.F.,1997, Heterocycles in Life and Society. ,Ed1st , John wiley & sons .
8. R.katritzky.A, 1984, Comprehensive Heterocyclic chemistry ., vol.5, p. 469-498.
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10. Shibata.S, Furukawa.M., and R.NakashimaR.N.,1976 ,Anal. Chem. Acta., 81, 131.
11. Abdulrazzaq.H.A.,2010, University of Kufa , Najaf, Eraq.
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19. Aboodflifel.I., Hussein Kadhim.S. , 2012, J. of kerbala university ,.
20. Majeed Rasheed.E., 2013, Diyala J. for pure Sciences , 9,1.
21. Shavaleev.N.M. &.Mohammad.N.K., 2013, Inorg. Chim. Acta, 20, 407, 261- 268 .
22. Pandey.A., Rajavel.R., Chandraker.S. & Dash.D., 2012, E-Jrournal of Chemisty , 9,4, 2524-2531.
23. Patnaik.L.N. & Das.S. , 1985, J.Am.Chem.Soc., 27, 2, 135 – 144 .
Published
2018-01-26
How to Cite
Abdualameer Jawad, S. (2018). Synthesis and characterization of azo amidazole ligand type N2 and metal complexes with di valence cobalt , nickel and copper. Al-Qadisiyah Journal of Pure Science, 22(3), 20 - 34. Retrieved from https://journalsc.qu.edu.iq/index.php/JOPS/article/view/598
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