Synthesis and characterization of azo amidazole ligand type N2 and metal complexes with di valence cobalt , nickel and copper

  • Shatha Abdualameer Jawad University of Karbala, College Of Edu. For Pure Sciences

Abstract

The bi dentate ligand type N2 have been prepared  through two steps . The first included the reaction between one equivalent of benzil with one equnivalent of hexa methylene tetra amine, the second included the reaction of first step precursor with one equnivalent of diazanium chloride ( p- ethyle aniline with acidic sodium nitrate )   ,  to obtained the target ligand . Co+2 , Ni+2 , Cu+2  from there action of the ligand Complexes were prepared with metal ions 1:1 ratio , the prepousd compounds were characterized by  FT-IR , UV-Vis , NMR for ligand , C.H.N Elemental analysis  spectoscopies , as well as the molar conductivity and magneticthe successptibility . suggested  geometry around the cobalte and copper  ions  is  octahedral and Square planer around nickel ion.
 

References

1. Sreekumar.N.V, Narayana.B , Hedge.P , Manjuantha.B.R & KSarojini.B, 2003, Micro Chmi. Acta., 74, 27.
2. Zollinger. H ,1987, Color Chemistry–Synthesis ,properties and application of organic dyes and pigments, VCH Publishers, NewYork.
3. Gung.B, Taylor.R, 2004, Parallel Combinatorial Synthesis of Azodyes, J. Chem., 1630,11.
4. Patal.S, 1975, The Chemistry of Hydrazo , Azo and Azoxy Group, Ed1st, John Wileg and Sons., London, New York .
5. Haider.Y.K.A and Mohammed.M.H, 2001, J.AL-Qadisiya Pure Sci., 14, 603.
6. Lycka.A and Hole+++++++cek.J, 2003, Dyes and Pigments., 57, 115.
7. Pozharskil.A.F.,1997, Heterocycles in Life and Society. ,Ed1st , John wiley & sons .
8. R.katritzky.A, 1984, Comprehensive Heterocyclic chemistry ., vol.5, p. 469-498.
9. Timmis.L.B. and Pyman.F.L, 1922, J. Soc. Dyes Colourists.,38, 269.
10. Shibata.S, Furukawa.M., and R.NakashimaR.N.,1976 ,Anal. Chem. Acta., 81, 131.
11. Abdulrazzaq.H.A.,2010, University of Kufa , Najaf, Eraq.
12. Bosque-Sendra.J.M, Loppez.E.A., and Garcia.A.M.,2003, Anal.Sci., 19, 1431.
13. Yamauchi.O.Y. and H.Tanaka.H.,1970, Talanta, 20, 203.
14. Daneshvar.N., Entezami.A.A, Khandar.A.A, and Saghatforoush.L.A,2003, Polyhedron, 22, 1437.
15. Hashim.Z. & Hassan.K.,2011, Iraqi National J.of Chemistry, 44, 474.
16. Mattison.L.E.,.Metaxas.J.M., andDell.C.S.O., 1969 , Anal. Chem.,41(12), 1690.
17. Nakamoto.K., Infrared and Raman spectra of Inorganic Coordination, 1997, 5th Ed. Part B, Joh N Wiley & Sons, New York, pp. 87, 154, 173 .
18..Al-Hyali.R.T.H., 2004, Thesis, M.Sc., University of Mosul, Mosul, Iraq.
19. Aboodflifel.I., Hussein Kadhim.S. , 2012, J. of kerbala university ,.
20. Majeed Rasheed.E., 2013, Diyala J. for pure Sciences , 9,1.
21. Shavaleev.N.M. &.Mohammad.N.K., 2013, Inorg. Chim. Acta, 20, 407, 261- 268 .
22. Pandey.A., Rajavel.R., Chandraker.S. & Dash.D., 2012, E-Jrournal of Chemisty , 9,4, 2524-2531.
23. Patnaik.L.N. & Das.S. , 1985, J.Am.Chem.Soc., 27, 2, 135 – 144 .
Published
2018-01-26
How to Cite
ABDUALAMEER JAWAD, Shatha. Synthesis and characterization of azo amidazole ligand type N2 and metal complexes with di valence cobalt , nickel and copper. Al-Qadisiyah Journal Of Pure Science, [S.l.], v. 22, n. 3, p. 20 - 34, jan. 2018. ISSN 2411-3514. Available at: <http://qu.edu.iq/journalsc/index.php/JOPS/article/view/598>. Date accessed: 22 june 2018.
Section
Articles