Synthesis and Spectroscopic Studies of new ligand N-((4-(phenylamino)phenyl)carbamothioyl)acetamide with some Divalent Metal Ion Complexes

  • Basima M.Sarhan Dep. Of chemistry, Collage of Education for pure sciences\ Ibn-AL-Hatham, University of Baghdadi.
  • Ban Z. Neema Dep. Of chemistry, Collage of Education for pure sciences\ Ibn-AL-Hatham, University of Baghdadi.
DOI: https://doi.org/10.29350/jops.2018.23.2.748

Abstract

A new ligand N-((4-(phenylamino) phenyl) carbamothioyl) acetamide (PCA) was synthesized by reaction of (4-amino di phenyl amine) with (acetyl isothiocyante) by using acetone as a solvent. The prepared ligand(PCA) has been characterization by elemental analysis (CHNS), infrared(FT-IR),electronic spectral (UV-Vis)&1H,13C- NMR spectra. Some  Divalent  Metal ion complexes of ligand (PCA) were prepared and spectroscopic studies by infrared(FT-IR), electronic spectral (UV-Vis), molar conductance, magnetic susceptibility and atomic absorption. The results measured showed the formula ofFall prepared complexes were [M (PCA)2 Cl2]    (M+2 = Mn, Co, Ni, CU, Zn, Cd &Hg),the proposed geometrical structure for all complexes wereeoctahedral.

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Published
2018-05-15
How to Cite
M.Sarhan, B., & Z. Neema, B. (2018). Synthesis and Spectroscopic Studies of new ligand N-((4-(phenylamino)phenyl)carbamothioyl)acetamide with some Divalent Metal Ion Complexes. Al-Qadisiyah Journal of Pure Science, 23(2), 152 - 160. https://doi.org/10.29350/jops.2018.23.2.748
Issue
Vol 23 No 2 (2018)
Section
Articles

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