Synthesis, Characterization and Antimicrobial activity of Azo-azomethine Metal Complexes
Keywords:
: Azo-azomethine , Au(III) , Ag(II) and Cu(II) complexes, Therapeutic (TGA) and Biological activity
Abstract
In the research, modern complexes also ligand (L) had been synthesized then characterized by using molar conductance measurements, (C.H.N.S), mass spectrum, magnetic susceptivity, “H1-NMR, (FT-IR)” Spectroscopy , (TGA), “UV-Visb.” Spectroscopy ,’X-ray studies” and scanning electron microscope (SEM). mole ratio [M:L] were [1:1] for Silver(I) also gold(III) ions but [1:2] to Copper(II) ion . The data optained from the various measurement indicater the Cu(II) and Ag(I) complexes have octahedral and tetrahedral geometry on respectively while square planar geometry for the Au(III) complex. We note that the copper complex [Cu(L)2Cl2] .H2O prepared has a high activity and sensitivity to the direction of the vital efficacy of coli Escherichia bacteria, but all prepared compounds have no activity against aureus Staphylococcus bacteria. As for alternaria fungi, we note that the silver complex of the prepared has a high effect and sensitivity to the direction of the vital efficacy of Alternaria fungi. The results will be clearly defined as shown in table 6 and shape (14)
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References
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29. Tian, Y., et al., Study on thermal stability and thermal decomposition mechanism of 1-((cyano-1-methylethyl) azo) formamide. Process Safety and Environmental Protection, 2021. 155: p. 219-229.
2. Salmam, N.S., H.K. Dakheel, and A.J. Kadhim, Study of thrmodynamic values in different temperature from partition coefficient for some organic acids immiscible di-solvents mixtures. Egyptian Journal of Chemistry, 2021. 64(12): p. 2-3
3. Erzunov, D., et al., Bulky-substituted phthalodinitriles and cobalt and copper phthalocyanines based on them: synthesis, thermal analysis and spectroscopic properties. Journal of Thermal Analysis and Calorimetry, 2020. 142(5): p. 1807-1816.
4. Sheykhi-Estalkhjani, A., et al., Synthesis and antibacterial evaluation of diaminomaleonitrile-based azo-Schiff bases and 8, 9-dihydro-7H-purine-6-carboxamides. Research on Chemical Intermediates, 2020. 46(8): p. 3835-3852
5. Mohsen, S. and W.H. Hoidy, Spectrophotometric Determination of Cobalt (II) and Lead (II) Using (1, 5-Dimethyl-2-Phenyl-4-((2, 3, 4-Trihydroxy Phenyl) Diazenyl)-1H-Pyrazol-3 (2H)-One) as Organic Reagent: Using It as Antimicrobial and Antioxidants. Nano Biomedicine & Engineering, 2020. 12(2).
6. Fahad, M.M., E.H. Zimam, and M.J. Mohamad, Synthesis and Antimicrobial Activity of Some New Barbituric Acid Derivatives Containing Thiazole Moiety from Sulfadiazine. Nano Biomed. Eng, 2019. 11(2): p. 124-137.
7. Kataki, S., S. Hazarika, and D. Baruah, Investigation on by-products of bioenergy systems (anaerobic digestion and gasification) as potential crop nutrient using FTIR, XRD, SEM analysis and phyto-toxicity test. Journal of Environmental Management, 2017. 196: p. 201-216.
8. Kakanejadifard, A., et al., Synthesis, structural characterization, X-ray, solvatochromism and biological properties of 7-hydroxy-2-(2-hydroxy-5-(phenyldiazenyl) benzylidene) amino)-4-phenyl-4H-chromene-3-carbonitrile. Journal of Molecular Liquids, 2016. 221: p. 211-215.
9. Szymańska, M. and I. Majerz, Theoretical Study of the Geometry of Dibenzoazepine Analogues. Molecules, 2022. 27(3): p. 790
10. Mahdi, E.S. and R.T.M. Al-Sa'edi, Preparation and Antibacterial Activity of New Azo-Schiff Thiazol Ligand and Some of its Metal Complexes. Nano Biomedicine & Engineering, 2018. 10(4).
11. Li, S., et al., Azopyridine-imidacloprid derivatives as photoresponsive neonicotinoids. Chinese Chemical Letters, 2016. 27(5): p. 635-639.
12. Arafath, M.A., et al., Synthesis, characterization and anticancer studies of Ni (II), Pd (II) and Pt (II) complexes with Schiff base derived from N-methylhydrazinecarbothioamide and 2-hydroxy-5-methoxy-3-nitrobenzaldehyde. Journal of Molecular Structure, 2017. 1130: p. 791-798
13. Onwudiwe, D.C., et al., Palladium (II) and platinum (II) complexes of N-butyl-N-phenyldithiocarbamate: Synthesis, characterization, biological activities and molecular docking studies. Inorganica Chimica Acta, 2016. 450: p. 69-80.
14. Alrammahi, F.A.-h., Preparation and Biological Activities of Some Heterocyclic Compounds Derivatives from 2-Aminothiazoles. Nano Biomed. Eng, 2018. 10(2): p. 129-140.
15. Onwudiwe, D.C., et al., Palladium (II) and platinum (II) complexes of N-butyl-N-phenyldithiocarbamate: Synthesis, characterization, biological activities and molecular docking studies. Inorganica Chimica Acta, 2016. 450: p. 69-80.
16. Chinnasamy, G., et al., Synthesis, characterization, antibacterial and wound healing efficacy of silver nanoparticles from Azadirachta indica. Frontiers in Microbiology, 2021. 12: p. 204.
17. Bi, R., et al., Facile synthesis and antibacterial activity of geraniol conjugated chitosan oligosaccharide derivatives. Carbohydrate Polymers, 2021. 251: p. 117099.
18. Erzunov, D., et al., Bulky-substituted phthalodinitriles and cobalt and copper phthalocyanines based on them: synthesis, thermal analysis and spectroscopic properties. Journal of Thermal Analysis and Calorimetry, 2020. 142(5): p. 1807-1816
19. Hamidian, K., R. Rahimi, and M. Hosseini-Kharat, Bisazo dye compounds based on aliphatic and aromatic diamine linking groups: Thermal behavior, chemical stability, electrochemical study, interaction with AgNPs and in vitro anti-pathogen activity. Inorganic Chemistry Communications, 2021. 128: p. 108559
20. Hameed, G.F., et al., Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor. Egyptian Journal of Chemistry, 2021. 64(3): p. 10-11.
21. Hameed, G.F., et al., Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor. Egyptian Journal of Chemistry, 2021. 64(3): p. 10-11.
22. Hameed, G.F., et al., Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor. Egyptian Journal of Chemistry, 2021. 64(3): p. 10-11.
23. Hameed, G.F., et al., Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor. Egyptian Journal of Chemistry, 2021. 64(3): p. 10-11.
24. Khammas, S., et al., Synthesis and Characterization of Chelating Phenolic Polymers Containing Metoclopramide Hydrochloride Drug. Egyptian Journal of Chemistry, 2021. 64(9): p. 4973-4984.
25. Saiga, K., et al., Optical Properties of Chiral Azo-Schiff Base Mn (II) and Zn (II) Complexes with Silver Nanoparticles. Journal of Materials Science and Chemical Engineering, 2021. 9(4): p. 1-10.
26. Waheeb, A.S., et al., New Thiazolyl Azo Ligand and Its Co (III), Cd (II) Complexes: Synthesis, Characterization, Cytotoxic and Computational Studies.
27. El-Bindary, A., et al., Polymeric complexes—LXII. Coordination chemistry of supramolecular Schiff base polymer complexes—a review. Journal of Molecular Liquids, 2016. 216: p. 318-329.
28. AL-Adilee, K.J., A.K. Abass, and A.M. Taher, Synthesis of some transition metal complexes with new heterocyclic thiazolyl azo dye and their uses as sensitizers in photo reactions. Journal of Molecular Structure, 2016. 1108: p. 378-397.
29. Tian, Y., et al., Study on thermal stability and thermal decomposition mechanism of 1-((cyano-1-methylethyl) azo) formamide. Process Safety and Environmental Protection, 2021. 155: p. 219-229.
Published
2023-03-20
How to Cite
Haitham kadhim Dakheel. (2023). Synthesis, Characterization and Antimicrobial activity of Azo-azomethine Metal Complexes. Al-Qadisiyah Journal of Pure Science, 27(1), 63-79. https://doi.org/10.29350/qjps.2022.27.1.1611
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Chemistry
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